Spectral Rate Theory for Two-State Kinetics
نویسندگان
چکیده
منابع مشابه
Spectral Rate Theory for Two-State Kinetics.
Classical rate theories often fail in cases where the observable(s) or order parameter(s) used is a poor reaction coordinate or the observed signal is deteriorated by noise, such that no clear separation between reactants and products is possible. Here, we present a general spectral two-state rate theory for ergodic dynamical systems in thermal equilibrium that explicitly takes into account how...
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Thomas C. T. Michaelsa, Lucie X. Liua, Samo Curkc, Peter G. Bolhuisd, Anđela Šarićc and Tuomas P. J. Knowlesa,e aDepartment of Chemistry, University of Cambridge, Lensfield Road, Cambridge, CB2 1EW, UK; bPaulson School of Engineering and Applied Sciences, Harvard University, Cambridge, MA 02138, USA; cDepartment of Physics and Astronomy, Institute for the Physics of Living Systems, University C...
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ژورنال
عنوان ژورنال: Physical Review X
سال: 2014
ISSN: 2160-3308
DOI: 10.1103/physrevx.4.011020